answersLogoWhite

0


Best Answer

The molecular geometry and electronic structure of styrene and methyl methacrylate as well as corresponding radicals formed by the addition of a methyl radical to the -carbon of the monomer were determined using the density functional theory at the B3LYP/6-311+G** level. Results were in good agreement with the theoretical and experimental data available in the literature. Full optimized molecular geometry of methyl methacrylate showed the trans form of the molecule. Monomers transformed into corresponding radicals preserved the main structural parameters of substituents whereas bonds between substituents and adjacent radical carbon atoms shortened. It was found that the correlation of the theoretically calculated electronic parameters for monomers and the corresponding radicals with the Q and e parameters from the Alfrey-Price scheme strongly depends on the level of calculations. Application of the higher level of theory including the correlation effect changes the relationship discussed in the literature between energy (EY) of formation of a radical from the monomer, the experimental e parameter, and the Q parameter and monomer/average electronegativity, respectively. The total atomic spin density at the radical carbon atom correlated with the radical parameter P in the Alfrey-Price scheme was computed to be higher for the methoxycarbonyl-1-methyl-ethyl radical when compared with the 1-phenyl-propyl radical. These values are in good agreement with the localization energies and the P values determined from the kinetic measurements for macroradicals ending with styrene and methyl methacrylate monomer units. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3761-3769, 2001

User Avatar

Wiki User

16y ago
This answer is:
User Avatar
More answers
User Avatar

Wiki User

9y ago

The geometry of electronic and molecular pairs are the same when they are in lone pairs. However, one of the biggest differences between these two are that electronic pair geometry is determined by lone pairs and bonds, while molecular geometry is determined by bonded atoms.

This answer is:
User Avatar

User Avatar

Wiki User

13y ago

the electronic geometry gives the rough starting shape of the molecule but once the electron configuration is added it changes the shape of the molecule from the original el.ectronic geometry to the more complex molecular geometry which is a sub-division of the starting electronic geometry

This answer is:
User Avatar

User Avatar

Wiki User

9y ago

electron pair geometry and molecular geometry won't be the same if there are lone pairs involved.

This answer is:
User Avatar

Add your answer:

Earn +20 pts
Q: What is the difference between molecular geometry and electronic geometry?
Write your answer...
Submit
Still have questions?
magnify glass
imp
Related questions

What is the difference between Electron Geometry and Molecular Geometry and explain the circumstances under which they will not be the same?

Check the link, it is a sheet describing the different types of electron and molecular geometry. It helped me a lot. ^^ electron pair geometry and molecular geometry won't be the same if there are lone pairs involved.


What is the difference between molecular geometry and molecular structure?

Molecular geometry is the distances and angles between the each of the different atoms in the molecule. It is essentially the shape of the molecule.Molecular structure includes the shape of the molecule, but also much more, such as its electronic structure. This includes the nature of the bonding in the molecule (such as where there are single, double or triple bonds), the polarity of the molecule (if the electrons are spread out evenly throughout the molecule or if they are concentrated in particular areas, and if so, what areas), etc.


How do you determine the molecular geometry of a molecule?

The molecular geometry of a molecule can be determined using the VSEPR theory. VSEPR (Valence Shell Electron Pair Repulsion) Theory: The basic premise of this simple theory is that electron pairs (bonding and nonbonding) repel one another; so the electron pairs will adopt a geometry about an atom that minimizes these repulsions. Use the method below to determine the molecular geometry about an atom. Write the Lewis dot structure for the molecule. Count the number of things (atoms, groups of atoms, and lone pairs of electrons) that are directly attached to the central atom (the atom of interest) to determine the overall (electronic) geometry of the molecule. Now ignore the lone pairs of electrons to get the molecular geometry of the molecule. The molecular geometry describes the arrangement of the atoms only and not the lone pairs of electrons. If there are no lone pairs in the molecule, then the overall geometry and the molecular geometry are the same. If the overall geometry is tetrahedral, then there are three possibilities for the molecular geometry; if it is trigonal planar, there are two possibilities; and if it is linear, the molecular geometry must also be linear. The diagram below illustrates the relationship between overall (electronic) and molecular geometries. To view the geometry in greater detail, simply click on that geometry in the graphic below. Although there are many, many different geometries that molecules adopt, we are only concerned with the five shown below.


What is the difference between geometry and solid geometry?

The difference between regular geometry and solid geometry is that regular geometry deals with angles, measuring angles, and theorem/postulates. Solid geometry deals with shapes and multiple sided figures.


What is the difference between molecular remission and cellular remission?

What is the difference between molecular remission and cellular remission?


What is the difference between a plane geometry and a solid geometry?

one is plane and one is solid


What is the difference between molecular compounds and molecular element?

mix


What is the difference between electronic and mechanical?

An electronic stopwatch gives a higher accuracy than a mechanical stop watch.


What is the difference between an electronic organ and electronic piano?

The difference between an electronic organ and an electronic piano is in the sounds produced. Sometimes, on the higher end models, the electronic piano will have a piano touch, weighted keyboard.


What is the difference between Print Media vs Electronic Media vs outdoor media?

Print media refers to newspapers, magazines, and brochures that are printed on paper. Electronic media includes television, radio, and the internet as platforms for communication. Outdoor media involves advertising displayed outdoors, like billboards, signages, and transit ads. Each type of media has its own strengths and reaches audiences in different ways.


What was the difference between solid analYtic geometry and plane analYtic geometry?

solid geometry deals with 3 dimensional figures while plane geometry deals with 2 dimensional.


Is As4O6 ionic or molecular?

According to the electronegativity difference between arsenic and oxygen, 1.26, it is molecular.