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Because a hexagon shape makes the honeycomb very strong, so less prone to damage, but how the bees know that is a mystery.
It is the most efficient use of space and gives the greatest number of cells for a given amount of wax.

Actually, if you look more closely at honeycomb the cell itself is more or less circular. It is just that they are arranged in a hexagonal pattern.

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Q: Why are honeycombs hexagon shaped?
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