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Fluorine and chlorine both need to gain electrons in order to achieve a stable electron configuration of 8 electrons in their outer shell, but fluorine is the smaller atom. As atoms get larger, their ability to attract electrons is reduced and they become more metallic in nature and less nonmetallic, because the outer shells of the electrons are farther from the positively charged nucleus, and even though the nucleus of larger atoms also has a larger positive charge, the increase in charge has less effect than the increase in distance, because charge is a direct proportionality and distance is an inversely squared proportionality. Distance matters more. So fluorine has the greater attraction for electrons, or as you put it, it has the greater reduction potential.

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Q: Why standard reduction potential of fluorine is greater than cl2?
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Related questions

What does reduction potential tell about the stability of an element?

The greater the reduction potential, the slower the element will oxidize.


What pair of half-reacations would have a negative total reduction potential?

If the reduction potential of the cathode is greater than that of the anode, there will be a negative total reduction potential (reaction will not proceed spontaneously).


Which has a greater electronegativity fluorine or francium?

Fluorine.


What will form a spontaneous reaction between two elements?

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Will form a spontanous redox reaction between two elements?

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What forms a spontaneous redox reaction between two elements?

The element with the greater reduction potential is the one that is reduced.


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when compared to oxygen, fluorine has greater electronegativity (greater attraction for shared pair of electrons).


Which one has a greater atomic mass fluorine or carbon?

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Which has a greater electron affinity fluorine or bromine?

Fluorine has greater electron affinity than bromine, or any other element.


Which has a greater atomic radius at atom of fluorine or an atom of beryllium?

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What is the reaction of fluorine with contact of water?

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