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Q: Why starch is mixed near the end point?
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Why is it that during titration of iodine or triiodine with thiosulphate the starch indicator should not be added until near the end point?

The Starch-Iodide complex is not very soluble in water, so the starch is added near the endpoint of an Iodine titration, when the Iodine concentration is low. This eliminates errors due to the fact that some Iodine may remain adsorbed on the complex and go undetected. so if you add the starch indicator only right near the end point when the solution is a light yellow colour the starch shouldn't complex and go lumpy.


Why is starch solution used as indicator in Sodium thiosulphate Iodine titrations instead of phenolphthalein indicator?

Phenolphthalein is an acid base indicator - it does not show the end-point in a thiosulfate type titration. Starch gives a very sharp end-point from a blue-black to colorless end-point when titrating iodine with thiosulfate. Phenolphthalein would just not detect this change.


Why starch is added in iodometric titration?

The color formed by reaction between starch and iodine is much more intense than the color of iodine itself, so that the end point can be determined more sensitively with than without starch.


Why iodine is used in starch hydrolysis test?

Iodine in water solutions is usually colored strong enough so that its presence can be detected visually. However, close to the end point, when the iodine concentration is very low, its yellowish color is very pale and can be easily overlooked. Thus for the end point detection starch solutions are used.


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What can be observed about the rate of change of pH of a solution near the end point of titration?

S


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