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No, because 100 v at 1 amp is a supply of 100 watts of power. It could be turned into a 25 v supply using a switch-mode voltage converter, but the available power would still be theoretically no more than 100 w, which is 4 amps at 25 v. In practice it would be slightly less.

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Q: Can 100 vdc 1 Amp be turned into 25 vdc 10 amps?
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