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The water. This is because it has greater positional disorder; if you know the position of one molecule you can say much less about the positions of all the others than you can in an ice crystal.

On the other hand, if we are maintaining the system at constant temperature and pressure, then at 0C the contribution to the entropy of the universe because of the water is the same whether it is liquid or solid. This is because when water freezes it give out a latent heat, increasing the entropy of its surroundings, which at 0C exactly cancels the ice's lower entropy.

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Q: Which has greater entropy liquid water at 0 degrees C or ice at 0 degrees C?
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Related questions

Why does the entropy of water increase as it warms from 0 degrees to 4 degrees?

Heat (in water) is random molecular motion, so greater heat equals greater disorder, hence more entropy.


What describes the phases of water Water expands as it changes from a solid to a liquid?

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