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If by "straight on" you mean at 90 degrees to the surface of the medium, that is because light is only deviated if it makes an angle with the normal, which is an imaginary line perpendicular to the surface of the medium. If no angle is made between the normal line and the light ray, then no refraction occurs and the light passes through in a straight line.

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Q: Why light passes undeviated falling straight on a refracting medium?
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