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there are two lone pairs on the oxygen of water but because of the orbital geometry, only one lone pair can have the correct orientation to make a bond and the other lone pair pointing away from the central atom, therefor water is monodentate not bidentate. and for bidentate ligands require distint lone pairs on distinct atoms.

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Q: Why water is monodentate For a ligand to be monodentate it must have ONE lone pair of electrons Water has two yet is not bidentate Why is this?
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