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100 sides
Most mathematicians use "100-gon." Hectogon and centagon are also permissible.
Triangle, Quadrilateral, Pentagon, Hexagon, Heptagon, Octagon, Nonagon, Decagon are 3-10. After that, they are usually just referred to as 11-gon, 12-gon, etc., but there is a latin naming system. See related links.