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not all congruent angles are vertical angles. Vertical angles must share a vertex.
opposite or vertical angles
have the same vertex. be congruent.
Vertical angles must be congruent so if they are complementary, they must be 45 degrees to be complementary.
In a Linear Pair the 2 angles add up to 180 degrees while Vertical Angles are just 2 vertical angles that are congruent.