Since one litre is one thousand milliliters, one hundred milliliters is one tenth
of one thousand.
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50 / 1,000 = 5 / 100 = 1 / 20
It is 100/1000 which can be simplified to 1/10. However, simplification results in a loss of information on the accuracy of the fraction: from a maximum error of approx 0.55% to 58%.
450/1,000 = 45/100 = 9/20
100ml is 1/10 of 1 litre.
It depends what you want it as a fraction of. It is 0.8 or 8/10 of a litre for instance.