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Based on the calculations in the related question (How many cubic feet of water vapor equals 1 pound?) using the Ideal Gas Law, 1 pound of water will be 27.24 cubic feet at 1 atmosphere pressure and 100°C (212°F).

1 gallon of water is 8.3454 pounds, so at the temperature 212°F and 1 atmosphere pressure, 1 gallon will generate 227.33 cubic feet.

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