You cannot associate volume and length without further information. However, if I make the assumption that you meant millilitres, then as there are 1000ml in a litre, there will be 4.5 litres in 4500ml.
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There are 1000 milliters (ml) in one liter.
450 ml is the fraction 450/1000 or 45/100 or 9/20 of a liter.
A kilogram is a measure of weight, whereas a milliliter is a measure of volume. The weight of 4500 ml depends on the density of the substance.
There are 1000 millilitres in one litre. Therefore, 450 millilitres is equal to 450/1000 = 0.45 litres.
There are 1000 millilitres in one litre. Therefore, 4500 millilitres is equal to 4500/1000 = 4.5 litres.