1 Milliter is = to .001 Liter
so yes it is smaller. "Milli" means one-thousandth.
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One liter is equal to 1000 milliliters.
Therefore 1 milliliter is 0.001 liters.
So a ml is actually 1/1000 of a liter and is much smaller.
So, to answer your question, milliliters are not greater than liters.