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Water because a liter is a measurement of space and not mass. Water occupying 1 liter of space is lots heavier than air occupying 1 liter of space.

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It depends on density. It is possible, given enough pressure, to have one liter of air weigh more than one liter of water.

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Q: What is heavier 1 liter of air or 1 liter of water?
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