In the case of linear optical transitions, an electron absorbs a photon from the
incoming light and makes a transition to the next higher unoccupied allowed state. When
this electron relaxes it emits a photon of frequency less than or equal to the frequency of
the incident light (Figure 1.3a). SHG on the other hand is a two-photon process where this
excited electron absorbs another photon of same frequency and makes a transition to
reach another allowed state at higher energy. This electron when falling back to its original
39
state emits a photon of a frequency which is two times that of the incident light (Figure
1.3b). This results in the frequency doubling in the output.
Chat with our AI personalities