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A centiliter is equal to ten milliliters. The metric system revolves around the number ten.
Each level is equal to ten times that of the previous level. Ten milliliters in a centiliter, ten centiliters in a deciliter, ten deciliters in a liter, ten liters in a decaliter, ten decaliters in a hectoliter and ten hectoliters in a kiloliter. This breakdown works for meters and grams too.
To answer your question, 2 cl equals 20 milliliters and two thirds of an ounce.
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