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1 Square Kilometer = 247.105381467165 Acres
One square kilometre is one million square metres. (one kilometre is one thousand metres, square kilometre is 1 000 times 1 000 metres)
One acre (an old fashioned unit of area) is 4 046.9 square metres.
So 16 square kilometres is 16 000 000 square metres.
16 000 000 divided by 4 046.9 equals 3953.6 acres.
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