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American Wire Guage. The smaller the number the larger the wire. As in an AWG 14/2 wire is much smaller than an AWG 10/2 wire.
American Wire Gauge ( AWG )
Use a wire table to find the cross-section area of #33 wire, multiply by 7, then find the AWG for that cross-section.
AWG 10.
A 100 amp service requires that you use AWG 4 copper wire or AWG 2 aluminum wire.