Service entrance wire should be AWG #3 copper.
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At that distance you will have a voltage drop of 81.25 volts if you use the recommended #6 wire on a 240 volt, 100 amp single phase circuit. Therefore I recommend you contact you electric utility and let them figure the voltage drop and the size wire required to safely run this distance. Using too small a wire can damage the electronics at the end of the run.
8 is the size of wire to use for grounding a 100 Amp panel. Green is color used for grounding8 is code.A #3 copper wire with an insulation rating of 75 or 90 degrees C is rated at 100 and 110 amps consecutively.
You need to look at the regulations that apply in your country. If in doubt, use a neutral wire of the same size as the live wire or wires.
6 AWG.
AWG 10.