There isn't really a good straight answer for that - if it's irregular, then it would completely depend on the hexagon...
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A single side cannot be perpendicular on its own. Two sides are perpendicular if they intersect at a 90 degree angle. There are many polygons, both regular and irregular, that can have perpendicular sides.
Hexagons come in many different shapes and sizes. As long as the figure has 6 straight edges and 6 angles, (with closed figure, of course) it's a hexagon. A regular hexagon though, has no perpendicular sides.A regular 6 sided hexagon has no perpendicular lines but it does have 3 pairs of parallel lines.
A hexagon has 6 sides A hexagon has 6 faces .sides.
A hexagon has 6 sides.