A 104-sided polygon is called a hecatontakaitetragon. The naming convention for polygons follows the Greek numerical prefixes for the number of sides, with "hecta" meaning 100 and "takaitetra" meaning 4. Therefore, a 104-sided polygon combines these prefixes to form its name.
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It's quite acceptable to call it a 104-agon but what's more important is knowing how to work out its properties.
A five sided polygon is called a pentagon because pentagon means five sided polygon I think.
A 12-sided polygon is called a dodecagon.
A million-sided polygon is called a megagon.
A 20-sided polygon is called an icosagon.
A 90-sided polygon is called an enneacontagon.