It is tessellating where there are no gaps or overlaps.
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A regular 5-sided shape is called a pentagon.
The general name for a plane shape with four sides is a quadrilateral.
A five sided shape is called a pentagon.
The total distance around a plane geometric shape, i.e. one drawn on a piece of paper, is called the shape's perimeter.
Six sided shapes are called hexagons. If all 6 sides are the same size, then the shape is called a regular hexagon.