it totally depends on triangle,side opposite to largest angle will be longest side.
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The longest side of a triangle is called the Hypotenuse.
The longest side of a triangle is opposite to its largest angle
obtuse triangle
In a right triangle (a triangle where one of the angles is exactly 90 degrees) , the longest side is called the hypotenuse. In non-right triangles, the longest side has no special name.
An obtuse triangle has an obtuse angle.