Well, geometrically, most slices are shaped like triangles, but it really depends on how you cut the pie. If you cut into halves, it'll be semicircle, thirds; it'll be 2 triangles and again, a semicircle. And so on.
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A slice, a segment or a sector.----------------A segment is the area of a circle between the chord and the arc. A "sector" is what you are looking for. See the links below.
Explode
That is approximately 14.14 square inchesArea of pie = pi r2 = pi (62) = about 113.1 square inches113.1 / 8 = about 14.137
That would depend on the shape of the L -- on ration between the horizontal and vertical parts.
You can explode it, meaning bringing it away from the rest of the pie. You could also make it a very different colour or pattern compared to the other slices.