No. A cube with sides which are 1 centimetre long or that of 1 inch are both unit cubes, as is a cube with sides of 1 decimetre (volume = 1 litre).
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Assuming you are using the same unit of measurement for the cubes and the boxes, you can fit 125 cubes in the box.
Depends on the size of the brick! If they are 1 unit cubes, then 4 rows of 16
48 unit cubes
you do not, one is a unit of measure, the other is a shape.