No, they cannot.
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No, angles that form a linear pair are supplementary.
Yes.
Not necessarily. A linear pair of angles must be supplementary but supplementary angles need not form a linear pair. For example, the opposite angles of a cyclic quadrilateral are supplementary but they are (by definition) not next to one another.
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All supplementary angles do not form a linear pair. The opposite angles of any quadrilateral inscribed in a circle (a cyclic quadrilateral) are supplementary but they are not a linear pair. However, all linear pair are supplementary.