No, but the can be adjacent angles. It is mathematically valid even though it serves no point.
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Supplementary Angles total 180o. A straight line is theoretically an angle of 180o. Draw a straight line (ruler) and draw another straight line from anywhere you like on it and at any angle you like. You have created a pair of supplementary angles!
180 degrees a straight angle.
Either pair can be greater..
totaly
No. All linear pair angles are supplementary, but supplementary angles do not have to be a linear pair.