Yep. ^.^
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In 2-d, the naming of polygons is such that a 10 sided shape is a decagon. Even if it is a 5-pointed star shape, it is a decagon. A concave decagon (rather than convex) but still a decagon. In 3-d, a decahedron, possibly, with the term "sides" being used for "faces".
The answer will depend on the units used in specifying "12 square" tile.
Yes, but only in the form of some irregular concave decagons.
it can in accompaniment with squares.
The whole point of tessellation is that infinitely many copies of the shape can be used to cover an infinite plane surface without gaps or overlap. So, obviously, the answer is infinitely many times!