No It cannot as the sum has to be below 180 degrees......
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Supplementary adjacent angles add up to 180 degrees
Yes, they can be adjacent as well as supplementary.
Supplementary angles.
Any angle that is supplementary is also adjacent. Two examples of a set of adjacent, supplementary angles are: 89 degrees and 91 degrees; or 100 degrees and 80 degrees.
Any pair of adjacent angles.