It is definitely toxic. I used to reuse them all the time but then i died 6 months ago from plasticolitis (a disease caused by reusing #2 plastic bottles).
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It would take 2.52 bottles to fill a gallon jug.
you fill the jug to the top and pour it into 2 equal jugs
fill the 5 gallon jug with water then pour the water into the 3 gallon jug until its full then u will have 2 gallons in the 5 gallon jug. then if the jugs both have the same circumference u can just make the water in both jugs level then u will have 2 gallons of water in each jug. pour the water from the 3 gallon jug into the 5 gallon jug. and u should know that 2+2=4 :)
Fill the 2, pour it into the three. Fill the 2 again and then pour both into the 5.
1 gallon is equal to 3.8 liters or 4 quarts, that is why they are refered to as quarts (one quarter gallon)