Yes, it must be 92.5% silver
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Sterling silver number charms are not very challenging to find at all. In order to find sterling silver number charms, one can visit the Charm Factory website.
It means that 99.8% of the mass is silver. Sterling has a minimum of 92.5%.
Sterling silver is stamped 925 or .925 because it is 92.5% silver, and 7.5% alloy (usually copper).
It means nothing at all - if it is stamped Sterling that means it is 92.5 percent silver - if it has no writing or stamping on it - it may or may not be silver - it means you should have it tested by a professional so you don't accidentally blind yourself with acid
It's 92.5% silver. There's a lot of helpful information on silver at link below.