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1 m^3 = 1 L 1,000,000 cm^3 = 1 L they r measured same way
an engine may have more than one cylinder. if a 4 cylinder engine has a displacement of 2.2 L, then each cylinder is 1/4 th of that or 0.55 L per cylinder.
Milliliter and liter
Use the volume fomula L*W*H
If by L, you mean litre, then it is impossible to compare the two, as one is a unit of distance, while the other is a unit of capacity.