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It depends on what you mean by bisect. All rectangles have diagonals that bisect the other one. Only certain rectangles (Squares) have diagonals that bisect its vertex, the ninety degree angle.
Complementary angles sum to give 90 degrees. Therefore the complement to an 85 degree angle is a 5 degree angle.
You find the center of a screwed 45 degree elbow by bisecting the angle.
With a protractor and a straight edge.
bisect