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Slightly more than 720,461 barrels. A single metric ton = 1,000kg. So in 100,000 metric tons there are 100,000,000kg (one-hundred million.) A standard barrel of oil weighs 138.8kg. (See link) So, 100,000,000 / 138.8 = 720,461.095 barrels.
1,183 litres of jet fuel in a metric tonne
That depends what the barrels are of and how much the individual barrels weigh.
About a thousand. One thousand litres of water weighs a tonne, and there is little difference in density between water and fuel.
There are 1000 kilograms (kg) in a metric ton (or tonne). And there are about 0.264 gallons in a litre. Also, the density of diesel fuel is right at about 0.85 kilograms per litre. Since you have a metric ton of diesel fuel, that is 1000 kilograms of diesel fuel, you need to know how many litres of diesel fuel you have. Divide 1000 kg by 0.85 kg/litre and you'll get about 1176.5 litres. Now convert that to gallons by multiplying 1176.5 litres by 0.264 gallons/litre and you'll get about 310.6 gallons of diesel fuel in that metric ton you started with.