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There is only one ace of hearts, but there is also an ace of clubs, an ace of diamonds and an ace of spades.
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The probability is 0 if you pick the the card from one end of a mint pack (2 of clubs) and 1 if you pick it from the other end (A spades). Also, if you pick 49 cards without replacement, the probability is 1. So, the answer depends on how many cards are drawn, and whether or not they are drawn from a well shuffled pack. The probability of getting an ace when one card is randomly picked from a pack is 4/52 = 1/13.