One kWh has 2.25 x 1025 eV. (The electron-volt is a very small unit, used in particle physics.)
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1 kilowatt hour = 3,600,000 Joules 1 Tetrajoule = 1,000,000 Joules 1 kilowatt hour = 3.6 Tetrajoules
Watt, kilowatt, or megawatt are units of power (energy/time). A watt is 1 joule/second. A kilowatt is a thousand joules per second. A kilowatt is also 1 kWh/hour (kilowatt-hour / hour). Since you would usually pay per kilowatt-hour, you might be more interested in the number of kilowatt-hours. A megawatt is a million joules per second - or a thousand kWh/hour.
Volts per hour is an invalid statement. You may have meant Watts per Hour.
1kilowatt = 1000 watts but you cannot compare a kilowatt hour to a watt, the extra dimension of time changes what is being measured. The watt is a measure of power. The watt second and the kilowatt hour is energy. The misunderstanding comes from our use of the term POWER COMPANY for our electricity suppliers. They bill us in kilowatt hours which is energy, not power.
1 kW.hr. = 3412.14 Btu. so 14 kW.hr. = 47,770 Btu.