This question cannot be answered sensibly. A litre is a measure of volume, with dimensions [L3]. A kilometre is a measure of distance, with dimensions [L]. Basic dimensional analysis teaches that you cannot convert between measures with different dimensions such as these without additional information.
The question is like asking how long is a bucketful of water.
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5000 m
Yes, 5 liters is equal to 5000 milliliters. There are 1000 milliliters in one liter, so to convert liters to milliliters, you multiply the number of liters by 1000.
It is not possible to answer this question, because kilometers is a measure of length, while liters is a measure of volume. It is like asking how long is the water in a glass.
They're exactly equal.
5000 kilometers