NONE!!!!
Because 'kilometres' is a metric measure of length. 'Acres' is an Imperial measure of area.
You cannot directly compare length with area. However, a length multiplied to a perpendicular length will give an area.
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The question, as stated, cannot be answered sensibly. An acre is a measure of area, with dimensions [L2]. A kilometre is a measure of distance, with dimensions [L]. The two measure different things and elementary dimensional analysis teaches that you cannot convert between measures with different dimensions such as these without additional information.
1 million (square meters) = 247.105381 acres
One million what?
2.5 acres
One kilometer
There are one million millimeters in a kilometer, so a millimeter would represent one millionth of a kilometer.