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A pascal is an SI unit of pressure = 1 newton / m2. An atmosphere is equal to the air pressure at sea level, which is 101325 pascals. Many barometers for measuring air pressure may have a scale for kilopascals, so 1 ATM = 101.325 kPa
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You cannot. kiloPascals is a measure of PRESSURE. Celsius is a measure of TEMPERATURE.
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