There are no kilometers in a hectare, as a kilometer is a measure of distance and a hectare is a measure of area.
If you want to compare the relationship between them though, it would be as follows:
1ha = (1km / 10)2
or:
1ha = 1km2/100
In other words, a hectare is equal in area to a square with a side length of one tenth of a kilometer.
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.01 sq km
1 hectare = 0.01 square kilometers.
1 hectare = 0.01 sq km.
0.01 km².
A kilometer is a unit of length, a hectare is a unit of area, so you can't compare the two. A square kilometer is equal to 100 hectares.