A mL is a unit for measuring a liquid, a mile is a distance measurement.
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If you're writing 'ml' to refer to a 'mile', then 1.609344 km = 1 mile. If you're writing 'ml' to refer to a 'milliliter', then the question has no meaning and thus no answer.
1 mile= 1 mile 5,280 feet= 1 mile
42.2 ml 1 centiliter = 10 milliliters 1 milliliter = 0.1 centiliter
10
1 mile =1.61 km