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There is no equivalence.

A milligram is a measure of mass. A millilitre is a measure of volume. The two measure different things and, according to basic principles of dimensional analysis, conversion from one to the other is not valid.

If you are not convinced, consider a millilitre of air. How many milligrams? Next consider a millilitre if Mercury. How many milligrams?

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12y ago

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Q: How many ml's are in 5 mg's?
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