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First, fill up the 5 gallon bucket. Then, pour the contents in the 5 gallon bucket into the 3 gallon bucket. This leaves 2 gallons left in the 5 gallon bucket. Pour the 2 gallons into the 3rd container. Now, fill the 5 gallon bucket again and pour the full 5 gallons into the 3rd container. This gives you 7 gallons.
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Volume is the measure of space. A 5 gallon bucket is roughly 1152 cubic inches.
Send me 20,000,000 nickels and I'll put them in a 5 gallon bucket counting as I go and then I'll tell you.