Metres and litres are two different types of measurements.
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Yes. A millimeter is 1/1000 (one thousandth) of a meter, and a centileter is 1/100 (one hundredth) of a meter, making the centiliter larger than the millimeter. It takes 10 milliliters to make 1 centiliter. The term "centiliter", by the way, is almost never used in scientific measurement or anywhere else for that matter - just on science and math tests.
Centiliter is a measure for volume and millimeter is for length/distance. Therefore, you cannot compare them.
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One millimeter is 0.393701 inches.
1 centiliter is 1/100 of a liter.