None.
A pound is a measure of weight whereas a ml is a measure of volume.
The weight of 4500ml depends on the density of the substance.
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4500 pounds = 2045.5 kg = 2.0455 tons
which is bigger 4 l or 4500 ml
562.5
yes
1 litre = 100 millilitres so 4.5 L = 4500 mL. Simple!