Rounding to "X" places means looking at the digit in the X+1 place and, if it is 5 of more adding 1 to the digit in X place. If it is less than 5 the digit in X place is left untouched.
In this case....
0.00033 has five decimal places. The third digit is 0, so the second digit is left as it is.
This means that 0.00033 is 0.00 rounded to two decimal places (or, "correct to two decimal places").
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8.588 rounded to two decimal places is 8.59.
57.50% rounded to two decimal places = 0.58
Leave it as it is because it is already in two decimal places
No, because it is already given to exactly two decimal places.
0.135 0.005 ------- 0.140 ------- Rounded to two decimal places the answer is 0.14