No, there is no smallest decimal number. Decimal numbers represent real numbers and between any two real numbers there are infinitely many other real numbers. So, there are infinitely many decimal numbers between 0 and your 1.02: each one will be smaller than 1.02
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64.0 is the smallest decimal
3.301*102 = 336.702
102 %
102 as 102/2 = 51 102/3 = 34
102