No.
The place values are Hundreds--Tens--Units.
So the 5 is in the Hundreds column and so it worth: five hundred.
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It's in the tens place so it's worth 50.
There are 5 tens
5 tens
There are zero tens in 5. The number 5 is a single-digit number, so it does not contain any tens. Tens are typically found in numbers with two or more digits, where the second place from the right represents the number of tens.
5 is in the "tens" place so its value is 5 tens, ie 50.