No.
8 pints is one gallon.
6 is less than that (obviously)
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8 pt = 1 gal ⇒ 40 pt = 40 ÷ 8 gal = 5 gal
(12 qt + 1 pt) is exactly equivalent to (25 pt).
1qt is bigger
1 gal is greater
1 qt = 2 pt → 4 qt = 4 x 2 pt = 8 pt < 16 pt → 16 pints is greater than 4 quarts.